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- W2079170055 abstract "When water oxidation by photosystem II (PSII) is impaired, an oxidized chlorophyll (Chl(Z)(+)) is formed that quenches excitation and may prevent photodamage. Both the identification of this Chl(+) and the mechanism of its oxidation and reduction are controversial. Using the available X-ray structures of PSII we calculated the efficiency of two proposed quenchers, Chl(Z)(+)(D1) and Chl(Z)(+)(D2). Of these two, only Chl(Z)(+)(D1) can quench to the degree observed experimentally. We also identify a chain of closely spaced pigments in the structure from Thermosynechococcus vulcanus that we propose to form a novel electron transport pathway between Chl(Z)(D1), beta-carotene, P680(+) and cytochrome b(559)." @default.
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- W2079170055 date "2003-04-30" @default.
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- W2079170055 title "The X-ray structure of photosystem II reveals a novel electron transport pathway between P680, cytochrome <i>b</i> <sub>559</sub> and the energy-quenching cation, Chl<sub>Z</sub> <sup>+</sup>" @default.
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- W2079170055 doi "https://doi.org/10.1016/s0014-5793(03)00442-3" @default.
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