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• W2079172852 abstract "The reactivity of σ-arylruthenium cyclometallate [Ru(LSB1)(PPh3)2Cl] [1; LSB1H2 = 4-methyl-2-(4-nitrobenzylideneamino)phenol] with nitric oxide (NO) gave rise to nitrosylation at the metal center, ring nitration, and oxidative cyclization, affording benzoxazole derivative formation. The molecular structure of the resultant nitrosyl complex, [Ru(LPB1)(PPh3)2(NO)Cl](ClO4) [2; LPB1H = 5-methyl-7-nitro-2-(4-nitrophenyl)benzoxazole] was determined, and a different σ-arylruthenium cyclometallate was characterized in which the benzoxazole derivative was found to be coordinated to the metal center. The crystal structure and IR and NMR spectral data confirmed the formation of a diamagnetic {RuNO}6 species with a S = 0 ground state and a {RuIINO+}6 description of the {RuNO}6 moiety. Coordinated NO in the resultant complex 2 was photolabile under visible light and was transferred to reduced myoglobin." @default.
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• W2079172852 date "2010-07-20" @default.
• W2079172852 modified "2023-09-23" @default.
• W2079172852 title "Oxidative Cyclization of a Phenolic Schiff Base and Synthesis of a Cyclometalated Ruthenium Nitrosyl Complex: Photoinduced NO Release by Visible Light" @default.
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• W2079172852 doi "https://doi.org/10.1021/ic1009847" @default.
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