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- W2079175989 abstract "The effect of metal complex on hydrogenation of o-chloronitrobenzene (CNB) over poly-vinylpyrrolidone-stabilized platinum clusters (PVP-Pt) has been studied in methanol at 303 K and atmospheric pressure. The addition of metal complexes to the catalytic system can considerably modulate both the activity and the selectivity of the catalyst. A low activity (0.41 mol H2/mol Pt s) and low selectivity (42.6%) were obtained when the neat PVP-Pt colloidal clusters were used as a catalyst. Upon the addition of the complexes Ni(AcAc)2 and Na[Co(AcAc)3], the better selectivity to o-chloroaniline (o-CAN) were promoted to 76.2% and 76.5%, and the higher activities (0.72 mol H2/mol Pt s and 0.83 mol H2/mol Pt s) were obtained, respectively. On the other hand, when the complex Ni(en)3Cl2 was introduced as a modifier, the highest selectivity to o-CAN (94.0%) was achieved, though the activity was lowered to 0.16 mol H2/mol Pt s." @default.
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- W2079175989 date "1999-07-01" @default.
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- W2079175989 title "Modification of metal complex on hydrogenation of o-chloronitrobenzene over polymer-stabilized platinum colloidal clusters" @default.
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- W2079175989 doi "https://doi.org/10.1016/s1381-1169(98)00337-9" @default.
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