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- W2079182023 abstract "The Cu,Zn superoxide dismutase catalyzes HCO(3)(-) -dependent oxidations by H(2)O(2). This activity has been shown to depend on the creation of a bound oxidant at the Cu(II) by interactions with H(2)O(2). The bound oxidant was then thought to oxidize HCO(3)(-) to CO(3)(.-), which diffuses into the bulk solution and there oxidizes diverse substrates. We now find that CO(2) rather than HCO(3)(-) facilitates the peroxidations catalyzed by Cu,Zn superoxide dismutase. This fact was shown by a lag in the rate of peroxidation of NADPH when NaHCO(3)(-) was added last and by a burst in the rate when aqueous CO(2) was added last. Both the lag and the burst were eliminated by carbonic anhydrase." @default.
- W2079182023 created "2016-06-24" @default.
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- W2079182023 date "2004-01-07" @default.
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- W2079182023 title "CO <sub>2</sub> , not documentclass[12pt]{minimal}usepackage{amsmath}usepackage{wasysym} usepackage{amsfonts} usepackage{amssymb} usepackage{amsbsy}usepackage{mathrsfs}setlength{oddsidemargin}{-69pt}begin{document}begin{equation*}{mathrm{HCO}}_{3}^{-}end{equation*}end{document}, facilitates oxidations by Cu,Zn superoxide dismutase plus H <sub>2</sub> O <sub>2</sub>" @default.
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- W2079182023 doi "https://doi.org/10.1073/pnas.0307635100" @default.
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