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- W2079182263 abstract "Various new chiral thioureas have been synthesized and used as ligands for the asymmetric hydroformylation of styrene catalyzed by rhodium(I) complexes. The best results were obtained with N-phenyl-N′-(S)-(1-phenylethyl)-thiourea associated to a cationic rhodium(I) precursor, and asymmetric induction of 40% was then achieved. As enantioselectivity is obtained with low conversions, various parameters have been examined in order to increase the catalytic activity without the loss of asymmetric induction." @default.
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- W2079182263 date "2000-05-01" @default.
- W2079182263 modified "2023-10-09" @default.
- W2079182263 title "Thioureas as new chiral ligands for the asymmetric hydroformylation of styrene with rhodium(I) catalysts" @default.
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- W2079182263 doi "https://doi.org/10.1016/s1381-1169(99)00401-x" @default.
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