Matches in SemOpenAlex for { <https://semopenalex.org/work/W2079189294> ?p ?o ?g. }
- W2079189294 endingPage "12379" @default.
- W2079189294 startingPage "12372" @default.
- W2079189294 abstract "The macrobicyclic mixed donor cage ligand AMME-N3S3sar (1-methyl-8-amino-3,13,16-trithia-6,10,19-triazabicyclo[6.6.6]eicosane) is capable of binding to Cu(II) as either a hexadentate (N3S3) or tetradentate (N2S2) ligand. The “Cu-in” (hexadentate)/“Cu-out” (tetradendate) equilibrium for the {Cu(AMME-N3S3sar)}2+ units is strongly influenced by both solvent (DMSO, MeCN, and water) and halide ions (Br– and Cl–). We have established a crucial role of the solvent in these processes through the formation of intermediate solvato complexes, which are substituted by incoming halide ions triggering a final isomerization reaction. Surprisingly, for reactions carried out in the usually strongly coordinating solvent water, the completely encapsulated N3S3-bound “Cu-in” form is dominant. Furthermore, the small amounts of the “Cu-out” form present in equilibrated DMSO or MeCN solutions revert entirely to the “Cu-in” form in aqueous media, thus preventing reaction with halide anions which otherwise lead to partial or even complete decomposition of the complex. From the kinetic, electrochemical, and EPR results, the existence of an outer-sphere H-bonded network of water molecules interacting with the complex inhibits egress of the Cu(II) ion from the cage ligand. This is extremely relevant in view of outer sphere interactions present in strongly hydrogen bonding solvents and their effects on Cu(II) complexation." @default.
- W2079189294 created "2016-06-24" @default.
- W2079189294 creator A5022088554 @default.
- W2079189294 creator A5027101876 @default.
- W2079189294 creator A5055404169 @default.
- W2079189294 creator A5057319709 @default.
- W2079189294 creator A5069005948 @default.
- W2079189294 date "2012-11-01" @default.
- W2079189294 modified "2023-10-17" @default.
- W2079189294 title "Reversible Rearrangements of Cu(II) Cage Complexes: Solvent and Anion Influences" @default.
- W2079189294 cites W1964326567 @default.
- W2079189294 cites W1965909779 @default.
- W2079189294 cites W1972835461 @default.
- W2079189294 cites W1985081821 @default.
- W2079189294 cites W1985690198 @default.
- W2079189294 cites W1989050436 @default.
- W2079189294 cites W1989925255 @default.
- W2079189294 cites W1994123481 @default.
- W2079189294 cites W1996972417 @default.
- W2079189294 cites W2009114372 @default.
- W2079189294 cites W2017590119 @default.
- W2079189294 cites W2044892102 @default.
- W2079189294 cites W2051398609 @default.
- W2079189294 cites W2053046402 @default.
- W2079189294 cites W2054774426 @default.
- W2079189294 cites W2055862959 @default.
- W2079189294 cites W2057919253 @default.
- W2079189294 cites W2062914210 @default.
- W2079189294 cites W2067040144 @default.
- W2079189294 cites W2071266512 @default.
- W2079189294 cites W2071767607 @default.
- W2079189294 cites W2084876188 @default.
- W2079189294 cites W2088206224 @default.
- W2079189294 cites W2092978833 @default.
- W2079189294 cites W2093322739 @default.
- W2079189294 cites W2110872450 @default.
- W2079189294 cites W2148049096 @default.
- W2079189294 cites W2163431348 @default.
- W2079189294 cites W2319152746 @default.
- W2079189294 cites W2319662711 @default.
- W2079189294 cites W2320656386 @default.
- W2079189294 cites W2321211652 @default.
- W2079189294 cites W2326531571 @default.
- W2079189294 cites W2952918769 @default.
- W2079189294 cites W3136451142 @default.
- W2079189294 doi "https://doi.org/10.1021/ic301696v" @default.
- W2079189294 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23116487" @default.
- W2079189294 hasPublicationYear "2012" @default.
- W2079189294 type Work @default.
- W2079189294 sameAs 2079189294 @default.
- W2079189294 citedByCount "6" @default.
- W2079189294 countsByYear W20791892942013 @default.
- W2079189294 countsByYear W20791892942014 @default.
- W2079189294 countsByYear W20791892942015 @default.
- W2079189294 countsByYear W20791892942017 @default.
- W2079189294 countsByYear W20791892942019 @default.
- W2079189294 crossrefType "journal-article" @default.
- W2079189294 hasAuthorship W2079189294A5022088554 @default.
- W2079189294 hasAuthorship W2079189294A5027101876 @default.
- W2079189294 hasAuthorship W2079189294A5055404169 @default.
- W2079189294 hasAuthorship W2079189294A5057319709 @default.
- W2079189294 hasAuthorship W2079189294A5069005948 @default.
- W2079189294 hasConcept C11111787 @default.
- W2079189294 hasConcept C112887158 @default.
- W2079189294 hasConcept C116569031 @default.
- W2079189294 hasConcept C126661725 @default.
- W2079189294 hasConcept C134431854 @default.
- W2079189294 hasConcept C145148216 @default.
- W2079189294 hasConcept C147789679 @default.
- W2079189294 hasConcept C148093993 @default.
- W2079189294 hasConcept C149823470 @default.
- W2079189294 hasConcept C161790260 @default.
- W2079189294 hasConcept C170493617 @default.
- W2079189294 hasConcept C171560689 @default.
- W2079189294 hasConcept C178790620 @default.
- W2079189294 hasConcept C179104552 @default.
- W2079189294 hasConcept C184651966 @default.
- W2079189294 hasConcept C185592680 @default.
- W2079189294 hasConcept C2780471494 @default.
- W2079189294 hasConcept C32909587 @default.
- W2079189294 hasConcept C55493867 @default.
- W2079189294 hasConcept C75473681 @default.
- W2079189294 hasConcept C8010536 @default.
- W2079189294 hasConceptScore W2079189294C11111787 @default.
- W2079189294 hasConceptScore W2079189294C112887158 @default.
- W2079189294 hasConceptScore W2079189294C116569031 @default.
- W2079189294 hasConceptScore W2079189294C126661725 @default.
- W2079189294 hasConceptScore W2079189294C134431854 @default.
- W2079189294 hasConceptScore W2079189294C145148216 @default.
- W2079189294 hasConceptScore W2079189294C147789679 @default.
- W2079189294 hasConceptScore W2079189294C148093993 @default.
- W2079189294 hasConceptScore W2079189294C149823470 @default.
- W2079189294 hasConceptScore W2079189294C161790260 @default.
- W2079189294 hasConceptScore W2079189294C170493617 @default.
- W2079189294 hasConceptScore W2079189294C171560689 @default.
- W2079189294 hasConceptScore W2079189294C178790620 @default.
- W2079189294 hasConceptScore W2079189294C179104552 @default.
- W2079189294 hasConceptScore W2079189294C184651966 @default.