FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2079203467> ?p ?o ?g. }

• W2079203467 endingPage "5401" @default.
• W2079203467 startingPage "5401" @default.
• W2079203467 abstract "Reaction of 3,5-(CF3)2PzLi with [Rh(μ-Cl)(η2-C2H4)2]2 or [Rh(μ-Cl)(PMe3)2]2 in Et2O gave the dinuclear complexes [Rh(η2-C2H4)2(μ-3,5-(CF3)2-Pz)]2 (1) and [Rh2(μ-Cl)(μ-3,5-(CF3)2-Pz) (PMe3)4] (2) respectively (3,5-(CF3)2Pz = bis-trifluoromethyl pyrazolate). Reaction of PMe3 with [Rh(COD)(μ-3,5-(CF3)2-Pz)]2 in toluene gave [Rh(3,5-(CF3)2-Pz)(PMe3)3] (3). Reaction of 1 and 3 in toluene (1 : 4) gave moderate yields of the dinuclear complex [Rh(PMe3)2(μ-3,5-(CF3)2-Pz)]2 (4). Reaction of 3,5-(CF3)2PzLi with [Rh(PMe3)4]Cl in Et2O gave the ionic complex [Rh(PMe3)4][3,5-(CF3)2-Pz] (5). Two of the complexes, 1 and 3, were studied for use as CVD precursors. Polycrystalline thin films of rhodium (fcc-Rh) and metastable–amorphous films of rhodium phosphide (Rh2P) were grown from 1 and 3 respectively at 170 and 130 °C, 0.3 mmHg in a hot wall reactor using Ar as the carrier gas (5 cc min−1). Thin films of amorphous rhodium and rhodium phosphide (Rh2P) were grown from 1 and 3 at 170 and 130 °C respectively at 0.3 mmHg in a hot wall reactor using H2 as the carrier gas (7 cc min−1)." @default.
• W2079203467 created "2016-06-24" @default.
• W2079203467 creator A5008766626 @default.
• W2079203467 creator A5019166964 @default.
• W2079203467 creator A5039090761 @default.
• W2079203467 creator A5065571692 @default.
• W2079203467 date "2012-01-01" @default.
• W2079203467 modified "2023-10-03" @default.
• W2079203467 title "Rhodium pyrazolate complexes as potential CVD precursors" @default.
• W2079203467 cites W1493916896 @default.
• W2079203467 cites W1964284432 @default.
• W2079203467 cites W1972268906 @default.
• W2079203467 cites W1975738408 @default.
• W2079203467 cites W1989249160 @default.
• W2079203467 cites W1992745920 @default.
• W2079203467 cites W1993216982 @default.
• W2079203467 cites W1994478853 @default.
• W2079203467 cites W1995294832 @default.
• W2079203467 cites W2001599272 @default.
• W2079203467 cites W2005864188 @default.
• W2079203467 cites W2009455372 @default.
• W2079203467 cites W2009590030 @default.
• W2079203467 cites W2019270500 @default.
• W2079203467 cites W2023007323 @default.
• W2079203467 cites W2025881364 @default.
• W2079203467 cites W2028972494 @default.
• W2079203467 cites W2030549006 @default.
• W2079203467 cites W2031339112 @default.
• W2079203467 cites W2033581801 @default.
• W2079203467 cites W2047662867 @default.
• W2079203467 cites W2047967909 @default.
• W2079203467 cites W2048805540 @default.
• W2079203467 cites W2053521849 @default.
• W2079203467 cites W2054130421 @default.
• W2079203467 cites W2054450506 @default.
• W2079203467 cites W2056928721 @default.
• W2079203467 cites W2058884288 @default.
• W2079203467 cites W2059462318 @default.
• W2079203467 cites W2068254332 @default.
• W2079203467 cites W2069273740 @default.
• W2079203467 cites W2074975439 @default.
• W2079203467 cites W2087500259 @default.
• W2079203467 cites W2089860649 @default.
• W2079203467 cites W2099958871 @default.
• W2079203467 cites W2109390871 @default.
• W2079203467 cites W2125226084 @default.
• W2079203467 cites W2134204040 @default.
• W2079203467 cites W2162675243 @default.
• W2079203467 cites W2166683310 @default.
• W2079203467 cites W2171331709 @default.
• W2079203467 doi "https://doi.org/10.1039/c2dt12450e" @default.
• W2079203467 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22392449" @default.
• W2079203467 hasPublicationYear "2012" @default.
• W2079203467 type Work @default.
• W2079203467 sameAs 2079203467 @default.
• W2079203467 citedByCount "5" @default.
• W2079203467 countsByYear W20792034672012 @default.
• W2079203467 countsByYear W20792034672013 @default.
• W2079203467 countsByYear W20792034672014 @default.
• W2079203467 crossrefType "journal-article" @default.
• W2079203467 hasAuthorship W2079203467A5008766626 @default.
• W2079203467 hasAuthorship W2079203467A5019166964 @default.
• W2079203467 hasAuthorship W2079203467A5039090761 @default.
• W2079203467 hasAuthorship W2079203467A5065571692 @default.
• W2079203467 hasBestOaLocation W20792034672 @default.
• W2079203467 hasConcept C145148216 @default.
• W2079203467 hasConcept C155647269 @default.
• W2079203467 hasConcept C161790260 @default.
• W2079203467 hasConcept C178790620 @default.
• W2079203467 hasConcept C185592680 @default.
• W2079203467 hasConcept C2182769 @default.
• W2079203467 hasConcept C2776442012 @default.
• W2079203467 hasConcept C2778142098 @default.
• W2079203467 hasConcept C2779782174 @default.
• W2079203467 hasConcept C2780263894 @default.
• W2079203467 hasConcept C2780654602 @default.
• W2079203467 hasConcept C521398313 @default.
• W2079203467 hasConcept C56052488 @default.
• W2079203467 hasConcept C8010536 @default.
• W2079203467 hasConceptScore W2079203467C145148216 @default.
• W2079203467 hasConceptScore W2079203467C155647269 @default.
• W2079203467 hasConceptScore W2079203467C161790260 @default.
• W2079203467 hasConceptScore W2079203467C178790620 @default.
• W2079203467 hasConceptScore W2079203467C185592680 @default.
• W2079203467 hasConceptScore W2079203467C2182769 @default.
• W2079203467 hasConceptScore W2079203467C2776442012 @default.
• W2079203467 hasConceptScore W2079203467C2778142098 @default.
• W2079203467 hasConceptScore W2079203467C2779782174 @default.
• W2079203467 hasConceptScore W2079203467C2780263894 @default.
• W2079203467 hasConceptScore W2079203467C2780654602 @default.
• W2079203467 hasConceptScore W2079203467C521398313 @default.
• W2079203467 hasConceptScore W2079203467C56052488 @default.
• W2079203467 hasConceptScore W2079203467C8010536 @default.
• W2079203467 hasIssue "17" @default.
• W2079203467 hasLocation W20792034671 @default.
• W2079203467 hasLocation W20792034672 @default.
• W2079203467 hasLocation W20792034673 @default.
• W2079203467 hasOpenAccess W2079203467 @default.

• next