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- W2079207767 abstract "Abstract Zn−Sn-alloy-coated steel sheets were prepared by a vacuum evaporation method to overcome the shortcomings of the conventional hot-dip-galvanizing and electrogalvanizing processes. The electrochemical behaviours of these alloy-coated steel sheets were evaluated in a neutral 3.5% NaCl solution. Zn−Sn alloy coatings with an Sn content lower than the eutectic composition consist of a simple mixture of Zn and Sn because of the poor solid solubility between them. During the coating process by vacuum evaporation, Sn tends to become enriched at the interface between the coating and the steel substrate by forming an FeSn 2 phase. During polarization in a neutral 3.5% NaCl solution, one passive region due to oxidation of Sn is always observed and a second passive region due to formation of zinc hydroxide may be observed at lower potentials if local alkalization by reduction of dissolved oxygen occurs preferentially on the Sn surface. The order of dissolution of the three elements from the Zn−Sn-alloy-coated steel sheet is Zn, Sn and Fe. The electrochemical test data suggest that the optimum composition is close to Zn−69.8wt.%Sn." @default.
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- W2079207767 date "1994-05-01" @default.
- W2079207767 modified "2023-09-27" @default.
- W2079207767 title "An electrochemical study on Zn−Sn-alloy-coated steel sheets deposited by vacuum evaporation. Part I" @default.
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- W2079207767 doi "https://doi.org/10.1016/s0257-8972(09)90010-x" @default.
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