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- W2079208731 abstract "Thermoanalytical studies of samples of thel-dipalmitoylphosphatidylcholine (DPPC)-water system containing from zero to about 90 g% water revealed that the small and broad endothermic peaks that appear at +4°C after storage at −20°C, converge into the so-called “subtransition” peak by an adequate annealing of a repeated thermal cycling between +4 and −4°C. On the basis of differential scanning calorimetry (DSC) thermograms for the annealed samples, a complete phase diagram composed of subtransition, pretransition, and main transition was established. Furthermore, thermal analysis of icemelting peaks in the present system indicates that in the thermodynamic stable phase below the subtransition there exists a “newly produced water,” which is in a state of aggregation lower than that of the “loosely bound water,” interposed between the bilayers of the DPPC molecules in the supercooledLβ′ gel phase and which plays a key role in the occurrence of the subtransition." @default.
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- W2079208731 date "1987-06-01" @default.
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- W2079208731 title "Role of water molecules in the subtransition of thel-dipalmitoylphosphatidylcholine-water system as studied by differential scanning calorimetry" @default.
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- W2079208731 doi "https://doi.org/10.1016/0021-9797(87)90410-3" @default.
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