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• W2079216114 abstract "Abstract— A photochemically induced reaction of1,3-dimethylthymine (DMT) with isopropanol leads to the formation of four alcohol adducts. The products have been identified as the cis and trans isomers of5,6-dihydro-1,3-dimethyll-6-(2-hydroxy-2-propyl) thymine (I and II), 2.4-diaza-8-hydroxy-2.4,6.8-tetramethylbicyclo[4.2.0]octan-1,3-dione (III), and5,6-dihydro-1,3-dimethyl-6-(2-oxo-l-propyl)-thymine (IV). An acetone photosensitized reaction of DMT with isopropanol gives the same products in a similar relative yield distribution. In both of these reactions, cyclobutane dimers of DMT are produced as well. Free radical reactions of 2-hydroxyisopropyl radicals with DMT, initiated by decomposition of di-t-butyl peroxide, leads to formation of only one of the cis and trans isomers described above. along with1,3-dimethyl-5-(2-hydroxy-2-methyl-1-propyl)uracil (V)." @default.
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• W2079216114 date "1979-02-01" @default.
• W2079216114 modified "2023-09-28" @default.
• W2079216114 title "PHOTOCHEMICAL AND FREE RADICAL INITIATED REACTIONS OF1,3-DIMETHYLTHYMINE WITH ISOPROPANOL" @default.
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• W2079216114 doi "https://doi.org/10.1111/j.1751-1097.1979.tb07046.x" @default.
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