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- W2079220565 endingPage "542" @default.
- W2079220565 startingPage "533" @default.
- W2079220565 abstract "Despite its enormous potential for the determination of polar compounds in water, the application of liquid chromatography-atmospheric pressure ionization-mass spectrometry (LC-API-MS) has some characteristic obstacles. Qualitative analysis of completely unknown compounds suffers from the limited resolution of quadrupole and ion-trap MS and the limited fragmentation encountered in collision-induced dissociation. Quantitation of target analytes in complex samples may be impaired by matrix effects, especially when using electrospray ionization. This review summarizes characteristic problems when using LC-MS for the qualitative and quantitative analysis of organic compounds in water. It outlines how some of the problems may be reduced by improved instrumentation (e.g. tandem MS or time-of-flight-MS), improved chromatographic separation or by measures taken before or after the LC-MS analysis. Because of the complexity of environmental samples, more effort in quality assurance and control is required." @default.
- W2079220565 created "2016-06-24" @default.
- W2079220565 creator A5072939366 @default.
- W2079220565 date "2001-10-01" @default.
- W2079220565 modified "2023-10-10" @default.
- W2079220565 title "The use of liquid chromatography-atmospheric pressure ionization-mass spectrometry in water analysis – Part II: Obstacles" @default.
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