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- W2079221460 abstract "The transient absorption spectrum of the tert-butoxyl radical in the UV region was obtained by the laser flash photolysis technique. The rate constants for β-scission and self-termination reactions of tert-butoxyl radicals were measured in five solvents; the Arrhenius parameters of the rate constant for β-scission kβ were determined. It was shown that both the solvent polarity and ability for hydrogen bonding accelerate the reaction of β-scission. The solvent effect on the rate constant of the β-scission reaction is discussed in terms of a simple Onzager−Betcher model, a point dipole model, and a model of the H-bonded complex of the radical with the solvent molecule." @default.
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- W2079221460 date "1998-09-19" @default.
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- W2079221460 title "Solvent Effect on the Rate of β-Scission of the <i>tert-</i>Butoxyl Radical" @default.
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- W2079221460 doi "https://doi.org/10.1021/jp9822236" @default.
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