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- W2079223416 abstract "Abstract The reaction of [ Cp ∗ MCl (μ 2 - Cl ) 2 MCp ∗ Cl ] ( M Ir , Rh ; Cp ∗ = η 5 - C 5 Me 5 ) with excess H2S gas for 5 min afforded the dobly bridged hydrosulfido complexes [ Cp ∗ MCl (μ 2 - SH ) 2 MCp ∗ Cl ] (3: M = Ir, 4: M = Rh) which were further transformed into the triply bridged cationic hydrosulfido complexes [ Cp ∗ M (μ 2 - SH ) 3 MCp ∗ ] Cl (5·Cl: M = Ir, 6·Cl: M = Rh) by continuous stirring under H2S. The molecular structures of 3, 4, 5 · [BPh4] and 6·Cl·C6H6 were determined by X-ray analyses. The SH ligands in complexes 3 and 4 take anti configuration in the solid state, whilst these complexes exist as mixtures of the syn and anti isomers in solution. Strong hydrogen bonds between the Cl anion and two of the SH ligands were found in 5·Cl and 6·Cl, and were maintained in CDCl4 solution. When complexes 3 and 4 were treated with NEt3 at room temperature, the cubane-type sulfido clusters [ Cp ∗ M ) 4 (μ 4 - S ) 4 ] (M = Ir, Rh) were produced in high yields. In the reaction of 3, an intermediary complex, most probably [ Cp ∗ Ir (μ 2 - S ) 2 IrCp ∗ ] , was detected by 1H NMR." @default.
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- W2079223416 date "1998-01-01" @default.
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- W2079223416 title "Syntheses, structures and properties of hydrosulfido-bridged diiridium and dirhodium complexes," @default.
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- W2079223416 doi "https://doi.org/10.1016/s0020-1693(97)05554-0" @default.
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