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• W2079232254 startingPage "8" @default.
• W2079232254 abstract "Sulfurization of five-coordinate [W(IV)O(1,2-benzenedithiolate)(2)](2-) proceeds under very mild conditions to form seven-coordinate [W(VI)O(eta(2)-S(2))(1,2-benzenedithiolate)(2)](2-), from which H(2)S was generated by treatment with H(2). This is the first functional model for the fourth tungsten-containing WOR4 enzyme. Kinetics and isotope-scrambling experiments have suggested the existence of six-coordinate W(V)(eta(1)-S(2)) species as a key reaction intermediate." @default.
• W2079232254 created "2016-06-24" @default.
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• W2079232254 date "2009-12-09" @default.
• W2079232254 modified "2023-10-13" @default.
• W2079232254 title "Reduction of Bis(dithiolene)oxo(disulfido)tungsten(VI) Complex with Dihydrogen Related to the Chemical Function of the Fourth Tungsten-Containing Enzyme (WOR4) from <i>Pyrococcus furiosus</i>" @default.
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• W2079232254 doi "https://doi.org/10.1021/ja907164s" @default.
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