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- W2079235881 endingPage "189" @default.
- W2079235881 startingPage "149" @default.
- W2079235881 abstract "A. Introduction B. Structures of acrylonitrile adducts (i) The structure and possible modes of coordination of acrylonitrile (ii) Type (a) complexes, bonded through the nitrile nitrogen: the nickel complex [Ni(NCCHCH,),]*+ [Zn,Cl,]*and the methacrylonitrile complex CuBrNCCMeCH, -._____........._________ ...... (iii) Type (b) complexes, bonded dihapto through the vinyl group (a) The iron(O) complex (q*-CH,CHCN)Fe(CO), (b) The nickel(O) complex (q*-CH,CHCN)Ni[P(OR),], (R= ort/ro-tolyl) .... (iv) Type (c) complexes containing bridging acrylonittile Iigands: the molybdenum(0) complex Mo,(CO),(PBu,),(~-CH,CHCN), and the copper(I) complex Cu,Cl,(Ir-CH,CHCN) (v) Bond lengths in acrylonitrile adducts C. Features of the spectra of acrylonitrile adducts (i) Type (a) complexes, bonded through the nitrile nitrogen (ii) Type (b) and (c) complexes, bonded through the alkene function or bridging . . D. TheLewisbasicityofacrylonitriIe (i) Basicity of the nitrile function. (ii) Basicity of the alkene function E. Reactions involving coordinated acrylonitrile (i) Reduction reactions of coordinated acrylonittile (ii) Oligomerization reactions of acrylonitrile (iii) Acrylonitrile complexes as catalysts" @default.
- W2079235881 created "2016-06-24" @default.
- W2079235881 creator A5009574185 @default.
- W2079235881 creator A5018558781 @default.
- W2079235881 creator A5030867746 @default.
- W2079235881 creator A5067668103 @default.
- W2079235881 creator A5090271952 @default.
- W2079235881 date "1982-07-01" @default.
- W2079235881 modified "2023-09-27" @default.
- W2079235881 title "The coordination chemistry of acrylonitrile" @default.
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