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• W2079237763 abstract "Abstract The temperature dependence of the relaxation dynamics of a dinuclear cobalt-tetraoxolene complex undergoing photoinduced valence tautomerism is reported and discussed. Two different regimes were detected, one at low (5–20 K) and a second at higher temperatures (20–35 K). The activation energy for the low temperature regime suggests a tunnelling process assisted by lattice phonons. In the thermally activated region the activation energy is far from that expected for the total-symmetric Co–O breathing mode, thus suggesting an important role for other internal vibrational modes." @default.
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• W2079237763 date "2007-10-01" @default.
• W2079237763 modified "2023-10-16" @default.
• W2079237763 title "Relaxation dynamics of a photoinduced di-cobalt-tetraoxolene valence tautomer" @default.
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• W2079237763 doi "https://doi.org/10.1016/j.ica.2007.01.020" @default.
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