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- W2079237813 abstract "The accurate prediction of the structure and thermodynamic properties of electrolyte solutions over a wide range of thermodynamic states has been the focus of an enormous number of studies. In spite of these efforts, there are still a number of issues that require more development, especially those concerning the description of the structure and thermodynamic properties of an electrolyte solution close to criticality (i. e., the critical point associated with the unmixing of an ionic solution into two liquid phases of different electrolyte concentration). Another relevant issue is the need of an improved description of the structure and thermodynamic properties for aqueous solutions of 2–2 electrolytes (and also for electrolytes of higher charge) at low concentrations. The vast majority of the efforts have focussed on the calculation of the structure and other properties of electrolyte solutions by statistical mechanical methods at the McMillan-Mayer level [1]: integral equations and computer simulation. In the first approach the ion-ion pair correlation functions gjl(r) are calculated by solving an appropriate set of Ornstein-Zernike (OZ) equations, that is supplemented with" @default.
- W2079237813 created "2016-06-24" @default.
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- W2079237813 date "2001-01-01" @default.
- W2079237813 modified "2023-09-27" @default.
- W2079237813 title "A new family of bridge functions for electrolyte solutions" @default.
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