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• W2079244246 startingPage "437" @default.
• W2079244246 abstract "The occupational exposure to cobalt/tungsten carbide (Co/WC) dusts causes asthma and interstitial fibrosis. The International Agency for Research on Cancer (IARC) recently classified the mixture Co/WC as probably carcinogenic to humans (group 2A). The mechanism of action of Co/WC involves particle driven generation of Reactive Oxygen Species (ROS) with consequent oxidative damage. The present study evaluates the reactivity of Co/WC dust toward glutathione (GSH) and cysteine (Cys). Co/WC oxidized thiols through a mechanism involving the generation of sulphur-centred radicals. The results are consistent with the oxidation taking place at surface active sites, a part of which is accessible only to Cys S-H groups, but not to GSH ones. Such a reaction, with consequent irreversible depletion of antioxidant defenses of cells, will potentiate the oxidative stress caused by particle and cell generated ROS." @default.
• W2079244246 created "2016-06-24" @default.
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• W2079244246 date "2008-01-01" @default.
• W2079244246 modified "2023-10-16" @default.
• W2079244246 title "The oxidation of glutathione by cobalt/tungsten carbide contributes to hard metal-induced oxidative stress" @default.
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• W2079244246 doi "https://doi.org/10.1080/10715760802350904" @default.
• W2079244246 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18712631" @default.
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