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• W2079244803 abstract "Reactions of Cp2U(NEt2)2 with the moderately acidic agents ROH and ArOH lead to the cleavage of the UNEt2 bonds and formation of di-cyclopentadienyl dialkoxides and diaryl oxides of uranium(IV). The yields of the new derivatives are strongly dependent on the bulk of the OR or OAr groups; they can undergo disproportionation or decomposition reactions with formation of tris-cyclopentadienyl derivatives of uranium(IV). With the high-sterically crowded 2,6-(But)2C6H3OH ligand only one UNEt2 bond is cleaved, with formation of the stable Cp2U(OAr)(NEt2) complex. The tris-cyclopentadienyl aryl oxides of uranium(IV) formed in the disproportionation reactions of the bis-cyclopentadienyl diaryl oxides have been also obtained by reaction of Cp3UNEt2 with ArOH." @default.
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• W2079244803 date "1986-03-01" @default.
• W2079244803 modified "2023-10-03" @default.
• W2079244803 title "Bis-cyclopentadienyl alkoxides and aryl oxides of uranium(IV). Influence of the steric hindrance of the R groups on the stability of the Cp2U(OR)2, Cp2U(OC6H4R)2 and Cp2U(OC6H3R2)2 derivatives" @default.
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• W2079244803 doi "https://doi.org/10.1016/0022-328x(86)80100-0" @default.
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