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- W2079246216 abstract "Abstract The alkyltitanium compounds Tp*Ti(OR)(CH3)2 [R= CH3 (9a), CH(CH3)2 (9b)C(CH3)3 (9c)], Tp*Ti[O-CH(OH3)2]2CH3 (10b), Tp*TiCl[O-CH(CH3)2]CH2Si(CH3)3 (11b and Tp*TiCl[O-C(CH3)3]CH2Si(CH3)3 (11c are prepared and characterised by the reaction of alkoxytitanium complexes Tp*Ti(OR)Cl2 [R = CH3 (6b), CH(CH3)2 (6d), C(CH3)3 (6e)] and Tp*Ti[O-CH(CH3)2]2Cl (7d)], respectively, with the corresponding Grignard reagents. These titanium alkyl complexes do not react with aldehydes. When a stronger electrophile such as t-butylisonitrile (12) used in the case of 11b an insertion reaction takes place to give the t-butyl imines of acetone (13)." @default.
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- W2079246216 date "1992-04-01" @default.
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- W2079246216 title "Darstellung und Reaktionen von Alkyl-Hydridotrispyrazolylborat-Komplexen des Titans" @default.
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- W2079246216 doi "https://doi.org/10.1016/0022-328x(92)83161-a" @default.
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