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- W2079248091 abstract "Sorption equilibrium and kinetics of NpO 2 + on dispersed particles of Na-montmorillonite were experimentally investigated by using a°batch technique and a°spectroscopic method, respectively. Considering the heterogeneity of sorption sites, we investigated the affinity spectra for the sorption of NpO 2 + . It was found that the spectrum for NpO 2 + was monomodal but asymmetrical and that the half-width at half-maximum of the spectrum was relatively broad, indicating that the sorption sites of surface of Na-montmorillonite are strongly heterogeneous. From the kinetic spectrum for NpO 2 + , two sorption processes could be distinguished. It was considered that the fast process is attributable to the sorption of NpO 2 + on the easily accessible outer surface of Na-montmorillonite particles and that the slower process is assigned to the sorption on the interlayer surface. Mean apparent activation enthalpies for the fast and the slow processes were evaluated as 19 ± 2 kJ/mol and 23 ± 3 kJ/mol, respectively." @default.
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- W2079248091 date "2000-09-01" @default.
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- W2079248091 title "Sorption equilibrium and kinetics of NpO<sub>2</sub><sup>+</sup>on dispersed particles of Na-montmorillonite" @default.
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- W2079248091 doi "https://doi.org/10.1524/ract.2000.88.9-11.705" @default.
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