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- W2079257864 abstract "The first metal carbonyl complexes with the uninegative tridentate 1,3-bis(arylimino)isoindoline (BAII) ligand have been prepared. Rhodium(I) forms a 4-coordinate complex of the type RhL(CO) and iridium(I) a 5-coordinate IrL(CO)2 complex. Changes in remote substituents on the BAII ligand are reflected in changes in the metal carbonyl stretching frequencies demonstrating the ability to selectively modify the electron density at the metal center. The coordinatively unsaturated RhL(CO) is quite reactive toward oxidative addition; stable alkyl- and acyl-rhodium(III) complexes have been prepared and isolated." @default.
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- W2079257864 date "1976-03-01" @default.
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- W2079257864 title "Rhodium(I) and iridium(I) carbonyl complexes with 1,3-bis(arylimino)isoindolines" @default.
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- W2079257864 doi "https://doi.org/10.1016/s0022-328x(00)91548-1" @default.
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