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- W2079263472 abstract "A series of novel colorimetric anion sensors bearing phenol O–H and hydrazone N–H groups were synthesized and their structures were confirmed by X-ray single-crystal diffraction. In DMSO/H 2 O (9:1, v/v) solutions, two-arm pincer type sensors 1 and 2 could bind Cl − through the collaboration of phenol O–H and hydrazone N–H groups. In DMSO/H 2 O (7.5:2.5, v/v) solutions, sensors 1 , 2 and 4 showed colorimetric single selectivity for AcO − . When AcO − was added to their solutions, dramatic color changes from orange to magenta were observed. Yet other anions such as F − , Cl − , Br − , I − , HSO 4 − and H 2 PO 4 − could not cause any color change. Comparison with compound 5 (the analogues of 1 – 4 , but not containing the O–H groups) indicates that the phenol O–H group plays a critical role in the anion-recognition process." @default.
- W2079263472 created "2016-06-24" @default.
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- W2079263472 date "2009-04-02" @default.
- W2079263472 modified "2023-10-17" @default.
- W2079263472 title "Simple colorimetric sensors with high selectivity for acetate and chloride in aqueous solution" @default.
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- W2079263472 doi "https://doi.org/10.1016/j.snb.2009.01.015" @default.
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