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• W2079264766 abstract "The compound [C5H10NH2][MnL2] [H2L=N-(2-hydroxynaphthalen-1-yl)sarcosine] has been synthesised and characterised using single-crystal X-ray crystallography, spectroscopy and magnetic susceptibility measurements. The crystallographic asymmetric unit displays two similar, independent [MnL2]− complex ions linked via piperidinium cations through hydrogen bonding. The complex ions are alternating and arranged in two non-interacting parallel chains. Each of the complex ions is six-co-ordinate with the donor atoms, provided by the two bifunctional tridentate sarcosinato ligands, being amine nitrogen atoms and carboxylate and naphtholate oxygen atoms. The anionic ligands are co-ordinated facially and are related by a crystallographic centre of inversion at the manganese ion. The mean bond distances MnOnaphtholate (1.885 Å), MnOcarboxylate (2.069 Å) and MnNamine (2.198 Å) for the two molecules point to a pseudo-compressed octahedral geometry about the Mn(III) ion consistent with a pseudo-Jahn–Teller compression. IR spectroscopy corroborates the unidentate co-ordination fashion of the carboxylate group of the sarcosinato ligand and confirms the presence of the piperidinium cation. The room temperature effective magnetic moment, (8χT)1/2, is indicative of spin-only paramagnetism. As shown by the temperature dependence of the reciprocal of the magnetic susceptibility (χ−1), the magnetic behaviour of [C5H10NH2][MnL2] in the temperature range 5–300 K is in conformity with the Curie–Weiss law, χ=C/(T−θ), with θ=−0.12 K." @default.
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• W2079264766 date "2001-07-01" @default.
• W2079264766 modified "2023-10-17" @default.
• W2079264766 title "Manganese(III) in a pseudo-compressed mixed-donor octahedral environment: synthesis, X-ray crystal structure and physicochemical properties" @default.
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• W2079264766 doi "https://doi.org/10.1016/s0277-5387(01)00816-6" @default.
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