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• W2079268934 abstract "Abstract Methyl isocyanide reacts rapidly with (NBu n 4 ) 2 Re 2 Cl 8 in ethanol at 25 °C give a green product, shown by X-ray crystallographic study to be (NBu n 4 ) [ReCl 5 (CNCH 3 )]. The [ReCl 5 (CNCH 3 )] − ion is essentially octahedral, with all cis Re-Cl distances in the range 2.316(7) A to 2.336(7) A and the trans ReCl distance equal to 2.343(6), thus indicating little or no structural trans effect by the isocyanide ligand. The failure to find any simple substitution product, such as Re 2 Cl 6 (CNCH 3 ) 2 , is consistent with other observations where strongly π-acid ligands cause degradation of MM multiple bonds, although we cannot entirely rule out the formation of a small amount of such a product, nor is the identity of the oxidizing agent that converts Re III to Re IV known. The compounds crystallizes in space group P2 1 /c with a = 11.255(3) A , b = 14.651(6) A , c = 16.274(6) A , β = 93.82(6)°, V = 2677(3) A 3 , and Z = 4. The structure was refined to R 1 = 0.065 and R 2 = 0.076 using 1558 reflections with I > 3σ(I) and corrected for absorption." @default.
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• W2079268934 date "1979-01-01" @default.
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• W2079268934 title "The reaction of the octachlorodirhenate(III) ion with methyl isocyanide giving the pentachloro(methylisocyano)rhenium(IV) ion" @default.
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• W2079268934 doi "https://doi.org/10.1016/s0020-1693(00)93453-4" @default.
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