FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2079270930> ?p ?o ?g. }

• W2079270930 endingPage "374" @default.
• W2079270930 startingPage "361" @default.
• W2079270930 abstract "The diorganophosphinous-N-(N′, N′, N″, N″-tetramethyl) guanidinides 1a and 1b and the organophosphonous-bis-N-(N′, N′, N″, N″-tetramethyl)guanidinides 2 and 3 are used as ligands towards carbonyls of zerovalent transition metals. In most cases coordination via phosphorus is observed. 1b and 2 act as PN-donors towards the (tetracarbonyl)molybdenum fragment, forming chelate complexes involving one five-membered ring. 3 acts as a PNN′-donor towards molybdenum carbonyls, forming a bicyclic chelate complex. X-ray structure determinations were performed for the octacarbonyldimanganese compound 7, the tricarbonylnickel complex 8 and the tetracarbonyliron derivative 10. The dimanganese compound 7 was found to be diaxially substituted with short MnC bonds but standard MnP bond lengths. The nickel compound 8 exhibited short PNi bonds, long NiC bonds and short CO bonds, consistent with enhanced π-back donation from metal to phosphorus. The coordination geometry at the iron atom in 10 was found to be trigonal bipyramidal with phosphorus in the axial position, strongly distorted towards square pyramidal." @default.
• W2079270930 created "2016-06-24" @default.
• W2079270930 creator A5016093605 @default.
• W2079270930 creator A5034722607 @default.
• W2079270930 creator A5041824234 @default.
• W2079270930 creator A5056081640 @default.
• W2079270930 creator A5089476171 @default.
• W2079270930 date "1997-02-01" @default.
• W2079270930 modified "2023-09-24" @default.
• W2079270930 title "N-(N′, N′, N″, N″-tetramethyl) guanidine-substituted phosphines as monodentate, bidentate or tridentate ligands in transition metal chemistry" @default.
• W2079270930 cites W1548480374 @default.
• W2079270930 cites W1965370723 @default.
• W2079270930 cites W1970227862 @default.
• W2079270930 cites W1978644523 @default.
• W2079270930 cites W1985207544 @default.
• W2079270930 cites W1989751879 @default.
• W2079270930 cites W1990148488 @default.
• W2079270930 cites W1994848446 @default.
• W2079270930 cites W1995372744 @default.
• W2079270930 cites W1998907006 @default.
• W2079270930 cites W2000942038 @default.
• W2079270930 cites W2010415851 @default.
• W2079270930 cites W2035734686 @default.
• W2079270930 cites W2039342305 @default.
• W2079270930 cites W2046597721 @default.
• W2079270930 cites W2066785423 @default.
• W2079270930 cites W2071031126 @default.
• W2079270930 cites W2071115929 @default.
• W2079270930 cites W2081772830 @default.
• W2079270930 cites W2085588369 @default.
• W2079270930 cites W2088564572 @default.
• W2079270930 cites W2088699238 @default.
• W2079270930 cites W2093189646 @default.
• W2079270930 cites W2128179591 @default.
• W2079270930 cites W2158067591 @default.
• W2079270930 cites W2343599183 @default.
• W2079270930 cites W1963599988 @default.
• W2079270930 doi "https://doi.org/10.1016/s0022-328x(96)06444-3" @default.
• W2079270930 hasPublicationYear "1997" @default.
• W2079270930 type Work @default.
• W2079270930 sameAs 2079270930 @default.
• W2079270930 citedByCount "19" @default.
• W2079270930 countsByYear W20792709302016 @default.
• W2079270930 countsByYear W20792709302017 @default.
• W2079270930 countsByYear W20792709302019 @default.
• W2079270930 countsByYear W20792709302020 @default.
• W2079270930 countsByYear W20792709302021 @default.
• W2079270930 crossrefType "journal-article" @default.
• W2079270930 hasAuthorship W2079270930A5016093605 @default.
• W2079270930 hasAuthorship W2079270930A5034722607 @default.
• W2079270930 hasAuthorship W2079270930A5041824234 @default.
• W2079270930 hasAuthorship W2079270930A5056081640 @default.
• W2079270930 hasAuthorship W2079270930A5089476171 @default.
• W2079270930 hasConcept C106773901 @default.
• W2079270930 hasConcept C111592845 @default.
• W2079270930 hasConcept C115624301 @default.
• W2079270930 hasConcept C155647269 @default.
• W2079270930 hasConcept C158842870 @default.
• W2079270930 hasConcept C161790260 @default.
• W2079270930 hasConcept C178516000 @default.
• W2079270930 hasConcept C178790620 @default.
• W2079270930 hasConcept C179104552 @default.
• W2079270930 hasConcept C185592680 @default.
• W2079270930 hasConcept C197404232 @default.
• W2079270930 hasConcept C544153396 @default.
• W2079270930 hasConcept C549387045 @default.
• W2079270930 hasConcept C68913812 @default.
• W2079270930 hasConcept C71240020 @default.
• W2079270930 hasConcept C7167053 @default.
• W2079270930 hasConcept C8010536 @default.
• W2079270930 hasConcept C92840921 @default.
• W2079270930 hasConceptScore W2079270930C106773901 @default.
• W2079270930 hasConceptScore W2079270930C111592845 @default.
• W2079270930 hasConceptScore W2079270930C115624301 @default.
• W2079270930 hasConceptScore W2079270930C155647269 @default.
• W2079270930 hasConceptScore W2079270930C158842870 @default.
• W2079270930 hasConceptScore W2079270930C161790260 @default.
• W2079270930 hasConceptScore W2079270930C178516000 @default.
• W2079270930 hasConceptScore W2079270930C178790620 @default.
• W2079270930 hasConceptScore W2079270930C179104552 @default.
• W2079270930 hasConceptScore W2079270930C185592680 @default.
• W2079270930 hasConceptScore W2079270930C197404232 @default.
• W2079270930 hasConceptScore W2079270930C544153396 @default.
• W2079270930 hasConceptScore W2079270930C549387045 @default.
• W2079270930 hasConceptScore W2079270930C68913812 @default.
• W2079270930 hasConceptScore W2079270930C71240020 @default.
• W2079270930 hasConceptScore W2079270930C7167053 @default.
• W2079270930 hasConceptScore W2079270930C8010536 @default.
• W2079270930 hasConceptScore W2079270930C92840921 @default.
• W2079270930 hasIssue "1-2" @default.
• W2079270930 hasLocation W20792709301 @default.
• W2079270930 hasOpenAccess W2079270930 @default.
• W2079270930 hasPrimaryLocation W20792709301 @default.
• W2079270930 hasRelatedWork W2034653044 @default.
• W2079270930 hasRelatedWork W2057756633 @default.
• W2079270930 hasRelatedWork W2057834499 @default.
• W2079270930 hasRelatedWork W2079270930 @default.
• W2079270930 hasRelatedWork W2086732444 @default.

• next