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- W2079291944 abstract "Pulsed plasma polymerization is adopted to synthesize alkaline anion-exchange membranes (AAEMs) with high contents of functional groups. The attenuated total reflection Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy and thermo gravimetric analysis demonstrate that the benzyltrimethylammonium cationic groups can be successfully introduced into the polymer matrix. The content of the quaternary nitrogen in pulsed plasma-polymerized membrane is up to 1.93 atom%. The ultra-flat and undamaged morphology structure of the AAEMs indicates a low plasma ablation effect in the pulsed plasma polymerization. The excellent properties of the pulsed plasma-polymerized AAEMs, including good adhesion to the substrate, acceptable chemical stability and thermal stability, high ion-exchange capacity (1.42 mmol g−1) and water uptake (59.73 wt%), interesting ionic conductivity (0.0205 S cm−1 in deionized water at 20 °C) and ethanol permeability (3.37 × 10−11 m2 s−1), suggest a great potential for application in direct alcohol fuel cells." @default.
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- W2079291944 date "2011-07-01" @default.
- W2079291944 modified "2023-10-08" @default.
- W2079291944 title "Pulsed plasma-polymerized alkaline anion-exchange membranes for potential application in direct alcohol fuel cells" @default.
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- W2079291944 doi "https://doi.org/10.1016/j.jpowsour.2011.02.073" @default.
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