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- W2079294577 abstract "The crystal structure of the compound with empirical formula [Cu (2, 2'-BP)Cl NO3]2 (BP: 2,2'-bipyridine) (1) has been determined. Crystals are triclinic, space group P-1 with a = 7.5152(12) A, b = 9.2531(14) A, c = 10.2834(16) A, a =112.181(2)o, b = 102.155(2)o, g = 105.617(2)o. The copper atom displays a (4+1) square pyramidal coordination, with the four in-plane bonds provided by one chloride ion, two nitrogen atoms from the 2,2'-bipyridine molecule and one oxygen from the nitrate group. The apical position corresponds to a chloride ion Cl(1') from a centrosymmetric neighboring moiety. The two symmetry related Cl ions bridge two copper atoms, generating a dimeric unit (Cu(1)-Cl(1) = 2.2726(11) A, Cu(1)-Cl (1') = 2.7093(13) A). Magnetic susceptibility measurements showed a weak ferromagnetic interaction between dimers" @default.
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- W2079294577 date "2004-12-01" @default.
- W2079294577 modified "2023-09-23" @default.
- W2079294577 title "PREPARATION, STRUCTURE AND PROPERTIES OF BIS (M2-CHLORO)-(NITRATO-O)-(2,2'-BIPYRIDINE-N.N')COPPER(II):[Cu(2,2'-BP)Cl NO3]2" @default.
- W2079294577 doi "https://doi.org/10.4067/s0717-97072004000400013" @default.
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