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- W2079295967 abstract "Die Identifizierung von 2-Ethyl-1,6-dioxaspiro[4.4]nonan (Chalcogran) als Aggregationspheromon bei Borkenkäfern gab Anlaß zu systematischen Untersuchungen solcher spirocyclischer Ketale. Vier verschiedene Synthesewege sind an insgesamt elf 1,6-Dioxaspiro[4.4]nonanen beschrieben. An Hand der Massenspektren dieser Verbindungen wird ein allgemeingültiges Fragmentierungsschema aufgestellt, das die Identifizierung ähnlicher Substanzen in biologischem Material erleichtern soll. Alkyl-1,6-dioxaspiro[4.4]nonanes; a New Class of Pheromones The identification of 2-ethyl-1,6-dioxaspiro[4.4]nonane as a principal aggregation pheromone of some bark beetles led to systematic studies on these spiroketals. Eleven 1,6-dioxaspiro[4.4]-nonanes are synthesised by four different methods. From the mass spectra of these compounds a characteristic fragmentation scheme is deduced which facilitates the identification of such compounds in biological material." @default.
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- W2079295967 title "Alkyl-1,6-dioxaspiro[4.4]nonane; eine neue Klasse von Pheromonen" @default.
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- W2079295967 doi "https://doi.org/10.1002/jlac.197919790102" @default.
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