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- W2079304319 abstract "X-Ray studies of a series of 1-ethynyl-8-methoxynaphthalenes with varying functional groups at the alkyne terminus show only small changes in the 1,5 MeO⋯spC contact distances (2.593–2.663 Å) despite the different through-bond electron-attracting powers of the terminal substituents. Replacement of methoxy with dimethylamino led to a chemical reaction when the alkyne's activating group was a carboxylic ester. The 1,5 N⋯spC interaction between a dimethylamino group and a triphenylsilylethyne group has a 1,5 Me2N⋯spC contact distance ca. 0.12 Å longer than for the corresponding methoxy case, indicative of a primarily steric interaction." @default.
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- W2079304319 date "2002-04-12" @default.
- W2079304319 modified "2023-10-13" @default.
- W2079304319 title "Interactions between alkynes and methoxy or dimethylamino groups in peri-naphthalene systems" @default.
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- W2079304319 doi "https://doi.org/10.1039/b201038k" @default.
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