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- W2079306099 abstract "Abstract Using 0.0025-cm−1 resolution Fourier transform laboratory spectra, a thorough analysis of the ν4 band of COF2 has been performed leading to an extensive (up to J = 77 and Ka = 46) and precise (±0.0002 cm−1) set of energy levels for the v4 = 1 vibrational state of this molecule. It proved not possible to reproduce these experimental levels when considering the v4 = 1 vibrational state as isolated, and it has been necessary to take into account the Coriolis-type resonance between the levels of this state and those of a nearby state located about 4 cm−1 below. In this way, an accurate band center (ν0(ν4) = 1243.26609 ± 0.00014 cm−1) and rotational and coupling constants were derived. These constants were then used to generate a comprehensive list of line parameters suitable for high-resolution atmospheric studies." @default.
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- W2079306099 date "1991-10-01" @default.
- W2079306099 modified "2023-09-26" @default.
- W2079306099 title "The ν4 band of carbonyl fluoride" @default.
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- W2079306099 doi "https://doi.org/10.1016/0022-2852(91)90303-r" @default.
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