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- W2079325551 abstract "The phosphorescence decay kinetics and transient triplet-triplet absorption of 2,6-dimethyl-4H-1-benzothiopyran-4-thione (DMBTPT) were recorded in deoxygenated n-hexane, n-hexadecane and 3-methylpentane solutions. The measurements of DMBTPT in the triplet state were performed using a flash photolysis system with an excimer laser as excitation source. The triplet state decay constant at infinite dilution (k0) and teh self-quenching rate constant (ksq) for DMBTPT at room temperature were determined from the Stern-Volmer equation. The results obtained confirm an essential contribution of the self-quenching process to the deactivation of the DMBTPT triplet state. The ksq values suggest that this process is diffusion controlled, similar to other thioketones. Moreover, an analysis of the temperature dependence of τ−1 at different concentrations of DMBTPT in 3-methylpentane provides further evidence for a viscosity-controlled deactivation process." @default.
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- W2079325551 date "1996-03-01" @default.
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- W2079325551 title "Decay dynamics of the triplet state of 2,6-dimethyl-4H-1-benzothiopyran-4-thione in solution" @default.
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- W2079325551 doi "https://doi.org/10.1016/1010-6030(95)04215-6" @default.
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