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• W2079330178 abstract "Branching ratios have been measured for the photodissociative ionization of O2, N2, CO, NO, CO2, H2O, NH3 and CH4 between 16.8 and 40.8 eV, using line sources. Inconsistencies in previous photoionization fragmentation patterns for NO and H2O at 21.2 eV, and for CH4 at 16.8 eV, have been clarified. The high energy state of CO+ has been found to decay predominantly to O+ + C, in contrast to a recent study. Partial cross sections for formation of high energy states in O2+ and CO2+ deduced from this study are substantially lower than those reported in a recent 304 Å photoelectron spectroscopic investigation. The NO+ decomposition at higher energy favors N+ + O, although the lower energy channel is O+ + N. Ionization from the inner (2s-like) valence states of CO2 and H2O leads to C+ and O+ fragments, respectively, with probable shattering of the molecular ion into atomic and ionic fragments." @default.
• W2079330178 created "2016-06-24" @default.
• W2079330178 creator A5044809120 @default.
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• W2079330178 date "1976-12-01" @default.
• W2079330178 modified "2023-09-27" @default.
• W2079330178 title "Photodissociative ionization in the 21–41 eV region: O2, N2, CO, NO, CO2, H2O, NH3 and CH4" @default.
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• W2079330178 doi "https://doi.org/10.1016/0020-7381(76)80088-5" @default.
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