Matches in SemOpenAlex for { <https://semopenalex.org/work/W2079331527> ?p ?o ?g. }
- W2079331527 endingPage "4106" @default.
- W2079331527 startingPage "4101" @default.
- W2079331527 abstract "The luminescence of lanthanide(III) ions emitting in the near-infrared region is ideally suited for telecommunications applications, and a number of applications have been developed. These are in general based on inorganic matrices, but polymer-based matrices would have advantages in device fabrication. In organic matrices, however, molecular vibrations in the matrix quench the excited state of luminescent lanthanide ions. Replacement of strongly quenching groups such as C−H oscillators by more weakly quenching groups enhances the luminescence lifetime and hence also the luminescence quantum yield. This article reports a synthesis route developed in order to deuterate all C−H groups that contribute to the quenching in an organic lanthanide complex. The luminescences of three near-infrared emitting lanthanide ions − Nd3+, Er3+, and Yb3+ − were measured. The maximum effect achieved upon deuteration is a factor of 2−3, but lifetimes remain in the microsecond region (1·Nd3+: 5.5 μs; 1·Yb3+: 52.3 μs; 1·Er3+: 5.4 μs)." @default.
- W2079331527 created "2016-06-24" @default.
- W2079331527 creator A5012553404 @default.
- W2079331527 creator A5045120040 @default.
- W2079331527 creator A5069203888 @default.
- W2079331527 date "2001-11-01" @default.
- W2079331527 modified "2023-10-11" @default.
- W2079331527 title "Increased Luminescent Lifetimes of Ln3+ Complexes Emitting in the Near-Infrared as a Result of Deuteration" @default.
- W2079331527 cites W1893257378 @default.
- W2079331527 cites W1963490320 @default.
- W2079331527 cites W1965556088 @default.
- W2079331527 cites W1966150090 @default.
- W2079331527 cites W1967446151 @default.
- W2079331527 cites W1969137131 @default.
- W2079331527 cites W1970803380 @default.
- W2079331527 cites W2005124374 @default.
- W2079331527 cites W2012986299 @default.
- W2079331527 cites W2028935730 @default.
- W2079331527 cites W2051917204 @default.
- W2079331527 cites W2061812846 @default.
- W2079331527 cites W2063016887 @default.
- W2079331527 cites W2063187261 @default.
- W2079331527 cites W2098477283 @default.
- W2079331527 cites W2102986384 @default.
- W2079331527 cites W2105156586 @default.
- W2079331527 cites W2126578481 @default.
- W2079331527 cites W2129989808 @default.
- W2079331527 cites W2133676706 @default.
- W2079331527 cites W2140528875 @default.
- W2079331527 cites W2141997074 @default.
- W2079331527 cites W2148659800 @default.
- W2079331527 cites W2151203617 @default.
- W2079331527 cites W2152031832 @default.
- W2079331527 cites W2154275193 @default.
- W2079331527 cites W2156041489 @default.
- W2079331527 cites W2799686016 @default.
- W2079331527 doi "https://doi.org/10.1002/1099-0690(200111)2001:21<4101::aid-ejoc4101>3.0.co;2-9" @default.
- W2079331527 hasPublicationYear "2001" @default.
- W2079331527 type Work @default.
- W2079331527 sameAs 2079331527 @default.
- W2079331527 citedByCount "89" @default.
- W2079331527 countsByYear W20793315272012 @default.
- W2079331527 countsByYear W20793315272013 @default.
- W2079331527 countsByYear W20793315272014 @default.
- W2079331527 countsByYear W20793315272015 @default.
- W2079331527 countsByYear W20793315272016 @default.
- W2079331527 countsByYear W20793315272017 @default.
- W2079331527 countsByYear W20793315272018 @default.
- W2079331527 countsByYear W20793315272019 @default.
- W2079331527 countsByYear W20793315272020 @default.
- W2079331527 countsByYear W20793315272021 @default.
- W2079331527 countsByYear W20793315272022 @default.
- W2079331527 countsByYear W20793315272023 @default.
- W2079331527 crossrefType "journal-article" @default.
- W2079331527 hasAuthorship W2079331527A5012553404 @default.
- W2079331527 hasAuthorship W2079331527A5045120040 @default.
- W2079331527 hasAuthorship W2079331527A5069203888 @default.
- W2079331527 hasBestOaLocation W20793315272 @default.
- W2079331527 hasConcept C120665830 @default.
- W2079331527 hasConcept C121332964 @default.
- W2079331527 hasConcept C121745418 @default.
- W2079331527 hasConcept C145148216 @default.
- W2079331527 hasConcept C147789679 @default.
- W2079331527 hasConcept C148869448 @default.
- W2079331527 hasConcept C158355884 @default.
- W2079331527 hasConcept C171001562 @default.
- W2079331527 hasConcept C178790620 @default.
- W2079331527 hasConcept C181500209 @default.
- W2079331527 hasConcept C184779094 @default.
- W2079331527 hasConcept C185592680 @default.
- W2079331527 hasConcept C192562407 @default.
- W2079331527 hasConcept C201770740 @default.
- W2079331527 hasConcept C34742353 @default.
- W2079331527 hasConcept C49040817 @default.
- W2079331527 hasConcept C75473681 @default.
- W2079331527 hasConcept C91881484 @default.
- W2079331527 hasConceptScore W2079331527C120665830 @default.
- W2079331527 hasConceptScore W2079331527C121332964 @default.
- W2079331527 hasConceptScore W2079331527C121745418 @default.
- W2079331527 hasConceptScore W2079331527C145148216 @default.
- W2079331527 hasConceptScore W2079331527C147789679 @default.
- W2079331527 hasConceptScore W2079331527C148869448 @default.
- W2079331527 hasConceptScore W2079331527C158355884 @default.
- W2079331527 hasConceptScore W2079331527C171001562 @default.
- W2079331527 hasConceptScore W2079331527C178790620 @default.
- W2079331527 hasConceptScore W2079331527C181500209 @default.
- W2079331527 hasConceptScore W2079331527C184779094 @default.
- W2079331527 hasConceptScore W2079331527C185592680 @default.
- W2079331527 hasConceptScore W2079331527C192562407 @default.
- W2079331527 hasConceptScore W2079331527C201770740 @default.
- W2079331527 hasConceptScore W2079331527C34742353 @default.
- W2079331527 hasConceptScore W2079331527C49040817 @default.
- W2079331527 hasConceptScore W2079331527C75473681 @default.
- W2079331527 hasConceptScore W2079331527C91881484 @default.
- W2079331527 hasIssue "21" @default.
- W2079331527 hasLocation W20793315271 @default.
- W2079331527 hasLocation W20793315272 @default.
- W2079331527 hasOpenAccess W2079331527 @default.