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• W2079333466 abstract "A set of regioisomeric pairs of tricyclic hydroquinones, analogues of antitumor 9,10-dihydroxy-4,4-dimethyl-5,8-dihydroanthracen-1(4H)-one (1) and other derivatives, were synthesized and their regiochemistry and NMR spectra assigned by using (1)H-detected one-bond (C-H) HMQC and long-range C-H HMBC, in good agreement with theoretical O3LYP/Alhrichs-pVTZ calculations. The 5-hydroxymethyl derivatives (11, 15, 19) showed a (3)J(H, H) coupling constant of methylene protons evidencing the presence of a seven-membered intramolecular hydrogen bonded ring, not observed for the 8-hydroxymethyl isomers." @default.
• W2079333466 created "2016-06-24" @default.
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• W2079333466 date "2011-03-31" @default.
• W2079333466 modified "2023-10-14" @default.
• W2079333466 title "NMR assignment in regioisomeric hydroquinones" @default.
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• W2079333466 doi "https://doi.org/10.1002/mrc.2745" @default.
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