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• W2079339531 abstract "Lattice dynamical calculations on trans-planar polyethylene chains containing conformational defects of the type GGTGG have been carried out. The purpose of the work is to predict the points in the vibrational infra-red and/or Raman spectrum at which a tight, (200) type, fold should show absorptions and/or scattering. Calculations are verified for the cyclic hydrocarbon C34H68 which contains two GGTGG defects. The usefulness and limitations of the vibrational spectrum as evidence for the existence of (200) tight folds are discussed. Two infra-red bands near 1342 cm−1 and a third near 700 cm−1 may indicate GGTGG defects in single crystals. Raman spectra seem insensitive to such defects." @default.
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• W2079339531 date "1980-10-01" @default.
• W2079339531 modified "2023-09-28" @default.
• W2079339531 title "Defect modes for (200), GGTGG, tight fold re-entry in polyethylene single crystals" @default.
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• W2079339531 doi "https://doi.org/10.1016/0032-3861(80)90076-2" @default.
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