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- W2079340929 abstract "We calculate the rate of heating that occurs in the middle atmosphere (50 – 105 km) due to four exothermic reactions involving members of the odd-hydrogen family. These reactions are O + OH → O2 + H, H + O2 + M → HO2 + M, H + O3 → OH + O2, and O + HO2 → OH + O2. The energy lost from vibrationally excited OH (produced in the third reaction) by spontaneous emission is explicitly accounted for by using detailed kinetic models, so that only a portion of the exothermicity of this reaction is converted into heat. The heating rates due to these four reactions are found to rival the oxygen-related heating rates conventionally considered in models of the middle atmosphere, e.g., those due to O + O + M → O2 + M, O + O2 + M → O3 + M, O2 + hv → O + O, and O3 + hv → O + O2 The conversion of chemical potential energy into molecular translational energy (heat) by these odd-hydrogen reactions is a significant source of energy in the middle atmosphere which has not been previously considered." @default.
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- W2079340929 date "1991-01-01" @default.
- W2079340929 modified "2023-09-27" @default.
- W2079340929 title "Middle atmosphere heating by exothermic chemical reactions involving odd-hydrogen species" @default.
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- W2079340929 doi "https://doi.org/10.1029/90gl02672" @default.
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