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• W2079341208 abstract "Both electronic and steric effects that might produce triplet ground-state silylenes are explored. Ab initio calculations with large basis sets and correlation corrections suggest that the linear 3B1 and bent 3A2 states of dilithiosilylene are several kcal mol−1 below the two lowest singlet states: 1A1 and 1A2. On the other hand, closed-shell singlet di-t-butyl silylene is predicted to be at least 10 kcal mol−1 below the lowest triplet state." @default.
• W2079341208 created "2016-06-24" @default.
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• W2079341208 date "1986-12-01" @default.
• W2079341208 modified "2023-10-14" @default.
• W2079341208 title "Potential triplet silylenes" @default.
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• W2079341208 doi "https://doi.org/10.1016/0009-2614(86)80127-0" @default.
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