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- W2079341774 abstract "The diffusion coefficient (D) of π-conjugated polymers containing ferrocene unit in the polymer main chain in a 1:1 mixture of CH2Cl2 and CH3CN was determined from peak oxidation current observed in cyclic voltammetry of the polymers. The D value of the polymers was in a range of about 1×10−12–5×10−12 m2 s−1, which was considerably smaller than those of ferrocene (D=470×10−12 m2 s−1) and 1,1′-bis(phenylethynyl)ferrocene (2) (D=68×10−12 m2 s−1) in accordance with the higher molecular weight of the polymer. Effects of the structure of the π-conjugated polymers on the D value are discussed." @default.
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- W2079341774 date "2001-12-01" @default.
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- W2079341774 title "Electrochemical determination of diffusion coefficient of π-conjugated polymers containing ferrocene unit" @default.
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- W2079341774 doi "https://doi.org/10.1016/s0022-328x(01)00941-x" @default.
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