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- W2079348567 abstract "Satisfactory kinetic determinations of several aliphatic 1,3-diols were difficult to obtain. Moreover the product distributions from each of these substrates suggest complex parallel mechanisms. However, the elimination kinetic of 2,4-dimethyl-2,4-pentanediol has been measured over the temperature range of 419.7–459.9°C and pressure range of 47–115 torr. The reaction carried out by employing a static system, in seasoned vessel, and in the presence of the free-radical inhibitor propene, proved to be homogeneous, unimolecular, and follows a first-order rate law. The products are acetone, isobutene, and H2O. The rate coefficient is expressed by the following Arrhenius equation: log k1(s−1)=(12.53±0.58)−(217.3±8.0) kJ mol−1 (2.303RT)−1. The pyrolytic elimination of this substrate is believed to proceed through a concerted six-membered cyclic transition-state type of mechanism. © 1997 John Wiley & Sons, Inc. Int J Chem Kinet 29: 851–854, 1997" @default.
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- W2079348567 date "1997-01-01" @default.
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- W2079348567 title "The gas-phase pyrolysis of several aliphatic 1,3-diols. The kinetic and mechanism of 2,4-dimethyl-2,4-pentanediol" @default.
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- W2079348567 doi "https://doi.org/10.1002/(sici)1097-4601(1997)29:11<851::aid-kin6>3.0.co;2-l" @default.
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