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- W2079355780 abstract "A theory of the diffusion-jump process in monatomic crystals is presented. The theory treats large atomic displacements causing diffusion jumps as a summation of phonon amplitudes. By using the Debye approximation to the phonon spectrum, a theoretical basis for the empirical Zener relation is established. The elastic theory gives a satisfactory quantitative account of (a) the motion energy; (b) the motion entropy; (c) the motion volume; (d) the isotope effect. Low-temperature diffusion phenomena may be examined because the theory employs a sufficiently general description of the phonon system. Attention is drawn to some enhanced diffusion effects caused by zero-point phonons. A quantum-mechanical calculation of diffusion rates for very light impurities is made with a model potential. Anomalous isotope effects are found at temperatures below the characteristic temperature of the localized mode. The relevance of these results to low-temperature annealing of radiation damage is discussed." @default.
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- W2079355780 date "1968-07-15" @default.
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- W2079355780 title "Atomic Migration in Monatomic Crystals" @default.
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