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• W2079360018 abstract "The regio- and stereoselective addition of chlorosulfonyl isocyanate to (+)-3-carene 1 resulted in β-lactam 2, which was converted to N-Boc-β-amino acid 4, β-amino ester 7, and carboxamide derivatives 18 and 20 via N-Boc activation and mild ring opening. The corresponding β-amino ester 7 was transformed to 2-thioxopyrimidin-4-one 11 and 2,4-pyrimidinedione 13. LAH reduction of 5 and 7 resulted in amino alcohols 6 and 8. The reaction of 8 with phenyl isothiocyanate, followed by cyclisation, furnished 1,3-oxazine 15." @default.
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• W2079360018 date "2003-12-01" @default.
• W2079360018 modified "2023-09-24" @default.
• W2079360018 title "Synthesis and transformation of novel cyclic β-amino acid derivatives from (+)-3-carene" @default.
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• W2079360018 doi "https://doi.org/10.1016/j.tetasy.2003.10.001" @default.
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