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- W2079361868 abstract "Irradiation of the pyrazin-2-ones (1) in methanol under oxygen gave the 3,6-epidioxypyrazin-2-ones (2), the N-alkyl-N-acyl-α-oxo amides (3), and the unusual products, N-alkyl-α-acyloxy-α-methoxy amides (4). The mechanism for the formation of these photoproducts is discussed. Furthermore, thermal or photochemical treatment of the 3,6-epidioxypyrazinones (2), which could be readily obtained by the reaction of (1) and singlet oxygen, gave the N-alkyl-N-acyl-α-oxo amides (3) and this reaction would provide a useful synthetic method for the α-oxo imides (3)." @default.
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- W2079361868 date "1988-01-01" @default.
- W2079361868 modified "2023-09-27" @default.
- W2079361868 title "Synthesis of stable 3,6-epidioxypyrazin-2-ones and α-oxo imides by photo-oxygenation of pyrazin-2-ones with singlet oxygen" @default.
- W2079361868 doi "https://doi.org/10.1039/p19880002921" @default.
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