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- W2079374807 abstract "The labile sesquiterpene hydrocarbon (−)-(1R,7S,10R)-cadina-3,5-diene was isolated from manuka oil (Leptospermum scoparium) by preparative gas chromatography, while its enantiomer is present in a chemotype of the liverwort Conocephalum conicum collected in southern Germany. The structure and absolute configuration was derived by NMR investigations, enantioselective gas chromatography and by conversion into a series of products of known stereochemistry by acid catalysed rearrangement, e.g. (−)-(7S,10R)-trans-calamenene, (−)-(7S,10R)-cadina-1(6),4,diene, (−)-(1R,7S,10R)-bicyclosesquiphellandrene and (−)-(1R,10R)-zonarene. In addition, (+)-δ-amorphene was identified as a constituent of L. scoparium, while (−)-δ-amorphene is present in vetiver oil. Both enantiomers of this sesquiterpene, which has not been described as a natural product so far, were prepared by rearrangement of an enantiomeric mixture of germacrene D isolated from Solidago canadensis." @default.
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- W2079374807 date "1997-04-01" @default.
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- W2079374807 title "Natural occurrence of both enantiomers of cadina-3,5-diene and δ-amorphene" @default.
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- W2079374807 doi "https://doi.org/10.1016/s0031-9422(96)00749-2" @default.
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