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- W2079383710 abstract "The enantioselective [2 + 2 + 2] cycloaddition of 1,6-diynes with α-methylene lactones and cyclic ketones gave various chiral spirocyclic compounds. The reaction proceeded with high enantioselectivity when the rhodium−xylylBINAP complex was used as a chiral catalyst. Not only exo-methylene cyclic compounds but also exo-methylene acyclic compounds could be used as coupling partners for diynes. The present protocol provides access to a new chiral library possessing a quaternary carbon center, including a spirocyclic system." @default.
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- W2079383710 date "2006-09-29" @default.
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- W2079383710 title "Highly Enantioselective Construction of a Chiral Spirocyclic Structure by the [2 + 2 + 2] Cycloaddition of Diynes and <i>exo</i>-Methylene Cyclic Compounds" @default.
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- W2079383710 doi "https://doi.org/10.1021/ja064257u" @default.
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