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• W2079387831 abstract "The adsorption of Li and Cs on CdTe(100) single crystals was investigated using different surface sensitive electron spectroscopies. Low-energy electron diffraction shows a number of surface reconstructions of the clean surfaces, influenced by the Cd/Te ratio. Deposition of Li shows a constant sticking probability, while Cs has a variable sticking probability, characteristic of island growth coalescing at a coverage of a monolayer. Li and Cs both form amorphous monoatomic layers. Large work-function changes of the CdTe surface as a function of Li and of Cs coverage were found at the initial stages of adsorption, indicating that Cs and Li atoms are to a large extent ionized on the surface (100) plane. The initial dipole moments for Cs and for Li were calculated with the Helmholtz equation ${mathrm{ensuremath{mu}}}_{mathrm{C}mathrm{s},mathrm{ensuremath{theta}}ensuremath{rightarrow}0}$ensuremath{approxeq}26 D and ${mathrm{ensuremath{mu}}}_{mathrm{L}mathrm{i},mathrm{ensuremath{theta}}ensuremath{rightarrow}0}$ensuremath{approxeq}3.2 D and using Topping plots ${mathrm{ensuremath{mu}}}_{0,mathrm{C}mathrm{s}}$=127.2 D and ${mathrm{ensuremath{mu}}}_{0,mathrm{L}mathrm{i}}$=4.22 D. Adsorption of oxygen on the cesium-covered surface raises the work function by ensuremath{Delta}ensuremath{varphi}=0.5ifmmodepmelsetextpmfi{}0.05 eV. Reflection-electron energy-loss spectra of the cesiated CdTe(100) surface at ${mathit{E}}_{mathit{p}}$=100 eV, recorded at a low temperature (96 K), show a characteristic Cs two-dimensional surface plasmon, ensuremath{Elzxh}${mathrm{ensuremath{omega}}}_{mathit{s}}$ at 2.05 eV, which disappears with rising temperature. During Cs growth a loss is observed at 26.6 eV which is assigned to Cs 5s core-level transitions." @default.
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• W2079387831 date "1995-07-15" @default.
• W2079387831 modified "2023-09-26" @default.
• W2079387831 title "Adsorption of Li, Cs, and O on CdTe" @default.
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• W2079387831 doi "https://doi.org/10.1103/physrevb.52.1852" @default.
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