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• W2079392726 endingPage "1894" @default.
• W2079392726 startingPage "1891" @default.
• W2079392726 abstract "Silicon dangling bonds (Si-DBs) in HfSiOx have been studied using first-principles calculations. Interestingly, our computational result revealed that the Si-DB-related gap state in HfSiOx locates in a much lower energy region than that in SiOx. This is because Hf atoms enhance the ionic character of the HfSiOx film, which in turn induces a positive charge at the Si site. We consider that the low-lying Si-DB level, which is now very near the N 2p state, contributes to the formation of strong Si–N bonds in HfSiON. The lower shift of the Si-DB level upon cation metal inclusion can be useful information not only for improving the electric properties of high-k gate stacks but also for developing prominent silicon–oxide–nitride–oxide–silicon (SONOS) nonvolatile memories where controllability of the charge trap level is a crucial issue." @default.
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• W2079392726 date "2007-04-24" @default.
• W2079392726 modified "2023-10-16" @default.
• W2079392726 title "Guiding Principle of Energy Level Controllability of Silicon Dangling Bonds in HfSiON" @default.
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• W2079392726 doi "https://doi.org/10.1143/jjap.46.1891" @default.
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