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- W2079396859 abstract "Abstract A model allowing for the prediction of the thermodynamically constrained accumulation of leachables migrating from polymeric containers has been developed. The model predicts accumulation based on three accumulation-limiting mechanisms: total available pool, solute solubility and solute partitioning. Equations relating a solute's solvent-water partition coefficients ( P o - w and P h - w ) and its aqueous solubility and partitioning properties have been developed. Thus, one can predict leachable accumulations from the physical dimensions of the system being studied (container weight and solution volume) and from the solute's partition coefficients. The maximal accumulation of the leachable in solution will be the lowest value predicted via the three accumulation-limiting mechanisms. The model has been successfully applied to the migration of 2-ethylhexanoic acid out of a styrene-butadiene-styrene block co-polymer and accurately predicts the accumulation behavior of this species as a function of solution pH." @default.
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- W2079396859 date "1992-01-01" @default.
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- W2079396859 title "Model for estimating the accumulation of solutes leaching from polymeric containers into parenteral solutions" @default.
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- W2079396859 doi "https://doi.org/10.1016/0378-5173(92)90363-7" @default.
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