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- W2079399209 abstract "Abstract Various 1,6-dithiaspiro heterocycles can be synthesized from 1,3-thiazole-5(4H) -thiones via 1,3-dipolar cycloadditions, Diels-Alder reactions, ring expansion of oxiranes, and C-alkenylation followed by radical cyclization. 1, 3-Thiazole-5(4H)-thiones with a vinyl substituent at C(4) are photochemically transformed into fused polycyclic compounds or, after C-alkylation to the corresponding 4,5-dihydro-5-mercapto-1,3-thiazoles, into fused bicyclic compounds via radical cyclization. With mCPBA, 1,3-thiazole-5(4H)-thiones are oxidized to thionoxides, which fail to undergo cycloaddition reactions." @default.
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- W2079399209 date "1991-04-01" @default.
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- W2079399209 title "Addition Reactions With 1,3-Thiazole-5(4<i>H</i>)-Thiones; Synthesis of Spirocyclic AND FUSED BICYCLIC SULFUR HETEROCYCLES" @default.
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- W2079399209 doi "https://doi.org/10.1080/10426509108040636" @default.
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