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- W2079400214 abstract "Dinuclear zinc(II) complexes [Zn(2)(bpmp)(mu-OH)](ClO(4))(2) (1) and [Zn(2)(bpmp)(H(2)O)(2)](ClO(4))(3) (2) (H-BPMP=2,6-bis[bis(2-pyridylmethyl)aminomethyl]-4-methylphenol) have been synthesized, structurally characterized, and pH-driven changes in metal coordination observed. The transesterification reaction of 2-hydroxypropyl p-nitrophenyl phosphate (HPNP) in the presence of the two complexes was studied both in a water/DMSO (70:30) mixture and in DMSO. Complex 2 was not reactive whereas for 1 considerable rate enhancement of the spontaneous hydrolysis reaction was observed. A detailed mechanistic investigation by kinetic studies, spectroscopic measurements ((1)H, (31)P NMR spectroscopy), and ESI-MS analysis in conjunction with ab initio calculations was performed on 1. Based on these results, two medium-dependent mechanisms are presented and an unusual bridging phosphate intermediate is proposed for the process in DMSO." @default.
- W2079400214 created "2016-06-24" @default.
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- W2079400214 date "2007-11-05" @default.
- W2079400214 modified "2023-10-16" @default.
- W2079400214 title "Structural, Kinetic, and Theoretical Studies on Models of the Zinc-Containing Phosphodiesterase Active Center: Medium-Dependent Reaction Mechanisms" @default.
- W2079400214 cites W1871776402 @default.
- W2079400214 cites W1967578871 @default.
- W2079400214 cites W1968981865 @default.
- W2079400214 cites W1969316745 @default.
- W2079400214 cites W1970850106 @default.
- W2079400214 cites W1971770529 @default.
- W2079400214 cites W1975026632 @default.
- W2079400214 cites W1976936226 @default.
- W2079400214 cites W1980533904 @default.
- W2079400214 cites W1980723175 @default.
- W2079400214 cites W1981748997 @default.
- W2079400214 cites W1982012739 @default.
- W2079400214 cites W1984269389 @default.
- W2079400214 cites W1987341910 @default.
- W2079400214 cites W1989060947 @default.
- W2079400214 cites W1993039491 @default.
- W2079400214 cites W1994103683 @default.
- W2079400214 cites W1994688377 @default.
- W2079400214 cites W1996175989 @default.
- W2079400214 cites W2000365585 @default.
- W2079400214 cites W2008584788 @default.
- W2079400214 cites W2011774732 @default.
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- W2079400214 cites W2019005510 @default.
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- W2079400214 cites W2041701452 @default.
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- W2079400214 cites W2050976748 @default.
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- W2079400214 cites W2068229472 @default.
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- W2079400214 cites W2069280517 @default.
- W2079400214 cites W2076985659 @default.
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- W2079400214 cites W2080182825 @default.
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- W2079400214 cites W2083819209 @default.
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- W2079400214 cites W2088296195 @default.
- W2079400214 cites W2088677737 @default.
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- W2079400214 cites W2111031224 @default.
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- W2079400214 cites W2131605171 @default.
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- W2079400214 cites W2165385828 @default.
- W2079400214 cites W2166813142 @default.
- W2079400214 cites W2321749951 @default.
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- W2079400214 doi "https://doi.org/10.1002/chem.200700104" @default.
- W2079400214 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17680569" @default.
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